Enhancing Separation and Filtration performances with CR6 Alumina in Composite Membranes

Composite membrane for filtration applicationsBaikowski is at the forefront of innovation in materials science. Our products enable research and technological advancements. Among the applications, there is the development of graphene oxide (GO) composite membranes anchored on α-alumina substrates as mentioned in the following scientific publication « Composite GO/Ceramic Membranes Prepared via Chemical Attachment: Characterisation and Gas Permeance Properties. »

By providing a stable and inert platform for GO deposition, the substrates enable the creation of composite membranes with finely tuned pore structures and enhanced separation capabilities in this study, essential for industrial applications.

The porous ceramic substrates made with our High Purity CR6 Baikalox® powder, provide the necessary resistance in high-temperature and corrosive environments where polymeric membranes will fail.

Potential Applications of Composite GO/ceramic membranes

These membranes exhibits enhanced stability and permeance, as well as tailored surface properties that can be employed in various industries to address critical separation and filtration challenges such as :

  • 🌟 Gas Separation: The composite membranes are suitable for applications in industrial gas separation processes, purification of natural gas, and carbon capture technologies thanks to their ability to selectively permeate certain gases while retaining others.
  • 🌟 Water Treatment: The hydrophilic and hydrophobic modifications enabled by chemical linkers such as PDA, GPTMS, and APTMS allow the membranes to effectively separate contaminants from water. This application is particularly relevant for wastewater treatment, desalination, and the removal of organic and inorganic pollutants from water sources.
  • 🌟 Chemical Processing: The composite membranes’ resistance to chemical products and thermal stability make them suitable for the separation of organic solvents, recovery of valuable chemicals, and purification of reaction products.
  • 🌟 Energy Sector: The selective permeation properties can be harnessed to separate hydrogen from other gases, which is a critical step in producing high-purity hydrogen for fuel cells and other energy applications.
  • 🌟 Environmental Protection: By enabling the effective separation of harmful gases and pollutants, these membranes can help reduce emissions and treat industrial effluents, supporting cleaner and more sustainable processes.

CR6 Benefits

CR6 is a high-purity α-alumina powder of our Baikalox® range of products, well known for its fine particle size and excellent sintering properties.

These characteristics make it an ideal material for creating dense and robust ceramic supports, which are essential for high-performance composite membranes.

High purity aluminaThe specific properties of CR6 in that application include:

  • 🌟 High Purity: this characteristic ensures minimal contamination, which is crucial for maintaining the integrity of the ceramic substrates and the GO layer deposited on them.
  • 🌟 Controlled Particle Size Distribution: It contributes to the creation of uniform macroporous structures. This uniformity is essential for consistent membrane performance, as it influences both gas and water permeance.
  • 🌟 Chemical Compatibility: compatibility of CR6 with various chemical linkers, such as polydopamine (PDA), 3-Glycidoxypropyltrimethoxysilane (GPTMS), and 3-Aminopropyltrimethoxysilane (APTMS), facilitated the effective anchoring of GO layers onto the ceramic substrates.
  • 🌟 Excellent Sintering Behavior: It allows the creation of mechanically strong and thermally stable supports.

In the referenced study, custom-made α-alumina disks with a ~2 mm thickness and a 22 mm diameter were employed as substrates. The disks were fabricated by pressing the CR6 alumina powder in a custom-made mold and sintering at 800°C for 30 hours and further at 1180°C for 2 hours. One side of the disk was polished until no obvious scratch was observed under visual inspection with a light microscope.

How CR6 Alumina Contributes to Membrane Performance?

One of the primary challenges in composite membrane technology is ensuring strong and stable adhesion of GO layers to ceramic substrates.
The success here is mainly due to :

  • 🌟 Enhanced Stability: The CR6-based substrates have showed remarkable stability, maintaining their structural integrity and performance under various conditions.
  • 🌟 The smooth and polished surface: these surface characteristics have ensured optimal interaction with the modifying agents (PDA, APTES, GLYMO) and the graphene-based nanocomposites.
  • 🌟 Thickness: The substrates have enabled the formation of composite membranes with precise thickness control, optimizing the membrane for different separation applications.

Our high purity CR6 alumina has proven to be a critical component in the advancement of composite membrane technologies. Its superior properties facilitate the creation of reliable and high-performing membrane supports, enabling the successful integration of graphene-based nanocomposites.

This synergy between high-purity alumina and advanced nanomaterials opens new possibilities for applications in gas separation, water purification, and other fields requiring durable and efficient membrane solutions.

Learn more on CR6 composite membrane application in the following study : A Combined Gas and Water Permeances Method for Revealing the Deposition Morphology of GO Grafting on Ceramic Membranes

 

Custom and ready-to-use oxides

Designing easy-to-use solutions in order to meet our customer needs, processes and applications, is part of our know-how and DNA. Indeed, Baikowski® provides various ready-to-use oxides including:

spray-dried powders and slurries.

Ready-to-use and ready-to-press oxides

Powder deagglomeration

Several methods of powder deagglomeration are used according to the desired particle size and distribution.

  • Jet milling is the easiest way to produce middle-size milled powders that offer a large size distribution composed of one or two populations.
  • Ball milling is a size reduction technique using only mechanical forces that enables a lower size distribution than jet milling.
  • Wet milling allows the production of smaller particle size and a narrower size distribution versus other milling methods.

Thanks to these different deagglomeration processes, Baikowski® has not only the ability to expand its product portfolio with products that offer specific physicochemical properties and a higher sintering reactivity, but also to control dispersion, morphology, composition, homogeneity at the powder grain level.

Ready-to-use and ready-to-press oxides benefits

Wet milling enables the design and production of ready-to-use slurries, spray-dried powders with or without binder and freeze-dried solutions.

Among the various benefits of ready-to-use or ready-to-press solutions, we can mention a
better flowability, an improved behavior while pressing ceramics and a perfect consistency of your final product.
 

Generally speaking, slurries and spray-dried powders have helped our customers develop unique solutions in various markets including energy, battery, health or 3D printing, by allowing the design of innovative materials.

As noticeable examples:

  • spray-dried powders have considerably improved the ceramic injection molding process by making the production of feedstocks easier.
  • ready-to-use slurries have been a major breakthrough in the Semicon industry by ensuring the absence of large particle counts in the Chemical Mechanical Planarization (CMP) process.
  • YbF3 nano-dispersions, already dispersed in the dental formulations, have allowed outstanding performances for restorative applications. Mathym®, the producer of nano-dispersions within the Baikowski ® group, is a key actor of this market.

Baikowski® 3N & 4N ready-to-use and ready-to-press offering

Taking into account all of the above, our BA15 and GEA6 high purity alumina products, as well as our ZTA/ATZ and spinel solutions are commercially available in slurry, spray-dry and ready-to-press forms.

Other products and custom designs upon request.

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Analytical skills & tailor-made oxide solutions

How do we characterise and design powders and slurries thank to our in-house analytical skills?

Listen to Livia MARRA explanations, our Senior Project Manager, in this short video.

 

Get updated and relevant information

 

” Hello, my name is Livia Marra. I have been working for Baikowski since 2012. I started as a trainee engineer before becoming a R&D project manager.

Baikowski is a 115-year-old company, specialized in high purity alumina and many other oxide powders.
Our headquarters and manufacturing plant are located in Poisy, in France. We have another manufacturing plant in the United States, a joint venture in Japan and several sales offices around the world.
Mathym joined us in 2019 and is specialized in nano-dispersions. This branch of Baikowski enables us to expand our product offering and expand in new markets such as the dental one.

We address several markets including automotive, electronics, medical, watch & jewelry, aerospace & defense and cover applications in ceramics, polishing and batteries.
With so many high-end applications, we have great analytical needs, either to respond to our client demands, or to anticipate their needs. That’s why we are always looking for ways to improve our products characterization. For this purpose, we bought the “Calvet Pro of Setaram” that provides us thermogravimetric and DSC analyses.

As an example, we use it to measure the moisture absorption of our alumina powders. In lithium-ion battery applications, we know we can’t have water as it would interfere with lithium metal. By figuring out the mass uptake by a powder during its exposure to a humidity air flow, we are able to calculate the absorption rate of a powder.

For catalytic applications, the device allows to inform customers on the acidity/basicity of our products, their ability to absorb different type of gas.

We can also assess the mass lost of a powder with blinder system or the decomposition temperature of a special product. In addition, we can carry out a synthesis knowing the transformation temperature of the powder.

As a conclusion, thanks to the flexibility of this device and our analytical skills, we can meet a lot of our customers’ expectations. ”

Learn more on customization

 

zilight®an ultra-small nanozirconia product

The nano-dispersion zilight® from Mathym®

Since zilight® is commercially available, it has been a growing success for our start-up Mathym®. In fact, zilight® meets high-end applications where small particle size is key and do not have real competitive products. Thanks to its high refractive index, this product is mainly targeted at the optics and photonics markets. However, the energy & environment markets should benefit from its properties for demanding and emerging technical applications such as fuel cells. When doped with yttria (YSZ), zilight® can also be a nanomaterial of choice for restorative dental applications.Nano-dispersion of zirconia zilight® by Mathym

Technical aspects of the nanozirconia product zilight®

zilight® is available either doped with yttria (YSZ), CeO2, Gd2O or undoped (ZrO2). Mathym’s know-how lead not only to high-end zirconia nanoparticles, but also to state-of-the-art nano-dispersions. zilight® is available dispersed in various solvents & resins:

  • water, alcohol, polyol, acetone, MEK
  • select organic solvents
  • methacrylate or acrylate-based resin
  • silicone oils, customer specific monomer mixture, e.g.: epoxy & fluorene (under development)

The solid content can go up to 70% depending on the dispersion medium.LED device shutterstock

zilight® nanomaterial applications

zilight® exhibits a very high refractive index, ideal in the design of high-end optical materials. Moreover, zilight® preserves a high level of transparency in nanocomposites. It will be your favorite nanofiller for encapsulation materials, improving visible LED device efficiency. It can also act as an additive for advanced ceramics (sintering aid), for display materials (refractive index enhancer), or for coatings (scratch resistance).

Do you want to know more?

See zilight® technical data

 

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